Published October 2016 | Version v1
Journal article Metadata-only

Pd-catalyzed terpolymerization of alkynes, CO, and ethylene: Modification of thermal property of polyketones

Creators

  • 1. Div. of Energy Systems Research, Ajou University, Suwon (Korea, Republic of)

Description

The terpolymerization of CO, ethylene, and additional olefins varies the properties of polyketones depending on olefins. In this study, monomer candidates for the terpolymerization of polyketones were expanded to alkynes, in addition to olefins. Thermal properties of polyketones were modified by adding aromatic alkynes during Pd-catalyzed terpolymerization with CO and ethylene. The Tm values of terpolymers were reduced to 192–215°C

Additional details

Publishing Information

Journal Title
Bulletin of the Korean Chemical Society
Journal Volume
37
Journal Issue
10
Series
11 refs, 4 figs, 2 tabs
Journal Page Range
p. 1657-1660
ISSN
0253-2964

INIS

Country of Publication
Korea, Republic of
Country of Input or Organization
Korea, Republic of
INIS RN
48049639
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKENES; ALKYNES; CARBON OXIDES; CATALYSTS; ETHYLENE; KETONES; MODIFICATIONS; POLYMERIZATION; THERMODYNAMIC PROPERTIES
Descriptors DEC
ALKENES; CARBON COMPOUNDS; CHALCOGENIDES; CHEMICAL REACTIONS; HYDROCARBONS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES