Quantized vortices around wavefunctions. II
Creators
- 1. Theoretical Chemistry Institute, University of Wisconsin, Madison, Wisconsin 53706
Description
Quantized vortices can occur around nodes of wavefunctions. This fact, discovered by Dirac (1931) but little noted since, is rederived here and examples are discussed. The derivation depends only on the wavefunction being single valued and continuous. Since the derivation does not depend upon the dynamical equations, the quantized vortices are expected to occur for many types of waves (i.e., electromagnetic, acoustic, etc.). Such vortices have appeared in the calculations (McCullough and Wyatt, Kuppermann) of the H + H2 molecular collisions and play a role in the chemical kinetics. In a companion paper, it is shown that quantized vortices occur when optical waves are internally reflected from the face of a prism or particle beams are reflected from potential energy barriers.
Additional details
Identifiers
- DOI
- 10.1063/1.1681900;
Publishing Information
- Journal Title
- The Journal of Chemical Physics
- Journal Volume
- 61
- Journal Issue
- 12
- Series
- J. Chem. Phys.
- Journal Page Range
- 5456-5459
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 6175887
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ATOM-MOLECULE COLLISIONS; HYDROGEN; SCHROEDINGER EQUATION; VORTICES; WAVE FUNCTIONS
- Descriptors DEC
- ATOM COLLISIONS; COLLISIONS; DIFFERENTIAL EQUATIONS; ELEMENTS; EQUATIONS; FUNCTIONS; MOLECULE COLLISIONS; NONMETALS
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent