Published December 15, 1974 | Version v1
Journal article

Quantized vortices around wavefunctions. II

  • 1. Theoretical Chemistry Institute, University of Wisconsin, Madison, Wisconsin 53706

Description

Quantized vortices can occur around nodes of wavefunctions. This fact, discovered by Dirac (1931) but little noted since, is rederived here and examples are discussed. The derivation depends only on the wavefunction being single valued and continuous. Since the derivation does not depend upon the dynamical equations, the quantized vortices are expected to occur for many types of waves (i.e., electromagnetic, acoustic, etc.). Such vortices have appeared in the calculations (McCullough and Wyatt, Kuppermann) of the H + H2 molecular collisions and play a role in the chemical kinetics. In a companion paper, it is shown that quantized vortices occur when optical waves are internally reflected from the face of a prism or particle beams are reflected from potential energy barriers.

Additional details

Identifiers

Publishing Information

Journal Title
The Journal of Chemical Physics
Journal Volume
61
Journal Issue
12
Series
J. Chem. Phys.
Journal Page Range
5456-5459
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
6175887
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ATOM-MOLECULE COLLISIONS; HYDROGEN; SCHROEDINGER EQUATION; VORTICES; WAVE FUNCTIONS
Descriptors DEC
ATOM COLLISIONS; COLLISIONS; DIFFERENTIAL EQUATIONS; ELEMENTS; EQUATIONS; FUNCTIONS; MOLECULE COLLISIONS; NONMETALS

Optional Information

Notes
Updated automatically by Metadata and Full-Text Enrichment Agent