Published October 19, 2009 | Version v1
Journal article

Crystal structure and thermal expansion properties of new compound La2Cu0.8Ge3

  • 1. College of Materials Science and Engineering, Guangxi University, Nanning, Guangxi 530004 (China)
  • 2. Key Laboratory of New Processing Technology for Nonferrous Metal and Materials, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China)
  • 3. College of Physics and Electronic Engineering, Guangxi University for Nationalities, Nanning, Guangxi 530006 (China)

Description

A new ternary compound La2Cu0.8Ge3 was synthesized and studied. The crystal structure of La2Cu0.8Ge3 was refined from X-ray powder diffraction data by Rietveld method. The new compound was found to have a tetragonal α-ThSi2 structure with space group I41/amd (No. 141), and a = 0.42807(2) nm, c = 1.45626(6) nm, Z = 2 and Dcalc = 6.931 g/cm3. The thermal expansion properties of La2Cu0.8Ge3 were investigated using high-temperature powder X-ray diffraction technique in the temperature range from 321 K to 753 K. Results show that its unit-cell parameters increase with increasing temperature. The coefficients of average lattice thermal expansion are α-baram=1.17x10-5K-1, α-barcm=1.09x10-5K-1 and α-barVm=3.42x10-5K-1.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jallcom.2009.06.069

Additional details

Identifiers

DOI
10.1016/j.jallcom.2009.06.069;
PII
S0925-8388(09)01219-5;

Publishing Information

Journal Title
Journal of Alloys and Compounds
Journal Volume
485
Journal Issue
1-2
Journal Page Range
p. 739-742
ISSN
0925-8388
CODEN
JALCEU

Optional Information

Copyright
Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.