Published December 1, 2011 | Version v1
Journal article Metadata-only

Electrochemical properties of graphite electrode in propylene carbonate-based electrolytes containing lithium and calcium ions

Creators

  • 1. Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan)

Description

Electrochemical properties of graphite electrode are studied in propylene carbonate (PC) electrolytes containing both LiN(SO2CF3)2 and Ca(N(SO2CF3)2)2 salts, and the influence of the salt concentrations on the intercalation/de-intercalation properties of graphite electrode is clarified. In the higher concentration electrolytes, reversible lithium-ion intercalation/de-intercalation at graphite electrode takes place. In contrast, only the exfoliation of graphite occurs in the lower concentration electrolytes. The effect of the salt concentrations on the electrochemical properties of graphite is discussed.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.electacta.2011.06.062

Additional details

Identifiers

DOI
10.1016/j.electacta.2011.06.062;
PII
S0013-4686(11)00959-5;

Publishing Information

Journal Title
Electrochimica Acta
Journal Volume
56
Journal Issue
28
Journal Page Range
p. 10450-10453
ISSN
0013-4686
CODEN
ELCAAV

Conference

Title
61. annual meeting of the International Society of Electrochemistry (ISE)
Dates
26 Sep - 1 Oct 2010
Place
Nice (France)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
43093058
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
CALCIUM IONS; ELECTROCHEMISTRY; ELECTRODES; ELECTROLYTES; GRAPHITE; LITHIUM; LITHIUM IONS; SALTS
Descriptors DEC
ALKALI METALS; CARBON; CHARGED PARTICLES; CHEMISTRY; ELEMENTS; IONS; METALS; MINERALS; NONMETALS

Optional Information

Copyright
Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.