Published May 1, 2005 | Version v1
Journal article

XANES Pb LIII spectra of mixed-valence compound: minium, Pb3O4

  • 1. Siberian Department of Russian Academy of Sciences, Nikolaev Institute of Inorganic Chemistry, Novosibirsk 630090 (Russian Federation)

Description

Mixed-valence compound Pb3O4 (minimum) has been studied using X-ray absorption near-edge structure (XANES) spectroscopy and DFT calculations. In spite of the presence of two valence states of lead [Pb(II) and Pb(IV)], the XANES spectrum of studied system is corresponding to apparently unified, an intermediate valence state of Pb. The explanation is related to the basics of XANES spectroscopy

Additional details

Identifiers

DOI
10.1016/j.nima.2005.01.168;
PII
S0168-9002(05)00244-5;

Publishing Information

Journal Title
Nuclear Instruments and Methods in Physics Research. Section A, Accelerators, Spectrometers, Detectors and Associated Equipment
Journal Volume
543
Journal Issue
1
Journal Page Range
p. 184-187
ISSN
0168-9002
CODEN
NIMAER

Conference

Title
15. international synchrotron radiation conference
Acronym
SR 2004
Dates
19-23 Jul 2004
Place
Novosibirsk (Russian Federation)

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
37033706
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ABSORPTION; ABSORPTION SPECTROSCOPY; ELECTRONIC STRUCTURE; LEAD; LEAD OXIDES; NUCLEAR MAGNETIC RESONANCE; SPECTRA; VALENCE; X RADIATION; X-RAY SPECTROSCOPY
Descriptors DEC
CHALCOGENIDES; ELECTROMAGNETIC RADIATION; ELEMENTS; IONIZING RADIATIONS; LEAD COMPOUNDS; MAGNETIC RESONANCE; METALS; OXIDES; OXYGEN COMPOUNDS; RADIATIONS; RESONANCE; SORPTION; SPECTROSCOPY

Optional Information

Copyright
Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.