Published October 15, 1991 | Version v1
Journal article

Structure of tetraiodides of copper(I) and bismuth(III), CuBiI4

  • 1. CNRS URA 200, Faculte des Sciences Pharmaceutiques et Biologiques, 75 - Paris (France). Lab. de Chimie Minerale Structurale

Description

Mr = 780.1446, cubic, Fd3m, a = 12.134(6) A, V = 1786(2) A3, Z = 8, Dm(293 K) = 5.7(1), Dx = 5.801(1) Mg m-3, Mo Kα, λ = 0.71069 A, μ = 35 mm-1, F(000) = 2568, T = 293 K, R = 0.041 for 132 independent reflections. The structure is characterized by an octahedral stacking of I atoms. Each I atoms is surrounded by three Bi atoms and eight Cu atoms. The sites of Bi atoms are half occupied. The sites of Cu atoms have an occupancy rate of 0.09 to 0.18. (orig.)

Additional details

Additional titles

Original title (French)
Structure du tetraiodure de cuivre(I) et de bismuth(III), CuBiI

Publishing Information

Journal Title
Acta Crystallographica. Section C: Crystal Structure Communications
Journal Volume
47
Journal Issue
10
Series
Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
Journal Page Range
2023-2025
ISSN
0108-2701
CODEN
ACSCE