Published January 1, 2007 | Version v1
Report

EXAFS analysis with self-consistent atomic potentials

Description

Theoretical EXAFS spectra generated by FEFF6 and FEFF8 are compared. As a test of the effect of charge transfer on EXAFS analysis, we examine the aqueous uranyl (UO22+) ion. We find that the major difference between FEFF8 and FEFF6 is the edge energy position of approximately 5 eV. Modest changes in the forward focusing multiple scattering path of the uranyl resulting with FEFF8 produce a better model of the measured hydrated uranyl spectrum

Availability note (English)

Available from AIP Conf. Proc., X-Ray Absorption Fine Structure (XAFS 13), edited by B. Hedman, et al., AIP : New York, Volume 882, pp. 135-37

Additional details

Publishing Information

Imprint Pagination
135 p.
Report number
ANL/BIO/CP--57990

Conference

Title
13. International Conference on X-Rays Absorption Fine Structure
Acronym
XAFS 13
Dates
9-14 Jul 2006
Place
Stanford, CA (United States)

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
40089037
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Conference, Non-conventional Literature
Descriptors DEI
ABSORPTION SPECTROSCOPY; FINE STRUCTURE; MULTIPLE SCATTERING; URANYL COMPOUNDS; X-RAY SPECTROSCOPY
Descriptors DEC
ACTINIDE COMPOUNDS; SCATTERING; SPECTROSCOPY; URANIUM COMPOUNDS

Optional Information

Contract/Grant/Project number
AC02-06CH11357
Funding organization
USDOE Office of Science (United States)