Published June 2008 | Version v1
Journal article Metadata-only

Rhenium(V) methylmercaptobenzimidazole complexes

Creators

  • 1. Innovatsionno-Tekhnologicheskij Tsentr Materialovedeniya Vladikavkazskogo NTs RAN i Pravitel'stva RSO-Alanii, Vladikavkaz (Russian Federation)

Description

Rhenium(V) complexes with 1-methyl-1-H-benzo[d]imidazole-2-thiol (L) and their ammonia and thiocyanate complexes have been synthesized. The composition, structure, and thermal stability of the compounds in question have been determined by thermal gravimetric analysis, IR spectroscopy, mass spectroscopy, and by measuring molar electric conductivity. It is demonstrated that ligand L is coordinated via sulfur atom in the compounds synthesized

Abstract (Russian)

Получены координационные соединения рения(V) с 1-метил-1-Н-бензо[d]имидазол-2-тиолом (L) и их аммиачные и тиоцианатные комплексы. Состав, строение и термическая устойчивость указанных соединений изучены методами термогравиметрического анализа, ИК спектроскопии, масс-спектрометрии и кондуктометрии. Показано, что лиганд L в синтезированных соединениях координирован посредством атома серы

Additional details

Additional titles

Original title (Russian)
Метилмеркаптобензимидазольные координационные соединения рения(В)

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
53
Journal Issue
6
Journal Page Range
p. 969-972
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
40088831
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMMONIA; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; ELECTRIC CONDUCTIVITY; HALIDES; HYDRATES; HYDROXIDES; IMIDAZOLES; INFRARED SPECTRA; MASS SPECTRA; MOLECULAR STRUCTURE; OXYHALIDES; PYROLYSIS; RHENIUM COMPLEXES; THIOCYANATES; THIOLS
Descriptors DEC
ANTITHYROID DRUGS; AZOLES; CARBONIC ACID DERIVATIVES; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; DRUGS; ELECTRICAL PROPERTIES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; HYDRIDES; HYDROGEN COMPOUNDS; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; THERMOCHEMICAL PROCESSES; TRANSITION ELEMENT COMPLEXES; YIELDS

Optional Information

Notes
15 refs., 2 tabs.