Published January 1991 | Version v1
Journal article

Synthesis and X-ray structure analysis of the polymer trimethylstannyl pertechnetate, {(CH3)3SnOTcO3}n

  • 1. Kernforschungszentrum Karlsruhe GmbH (Germany, F.R.). Inst. fuer Heisse Chemie
  • 2. Heidelberg Univ. (Germany, F.R.). Anorganisch-Chemisches Inst.

Description

Reaction of Tc2O7 with (CH3)4Sn yields besides {(CH3)3SnOTcO3}n (5) also CH3TcO3 (4) and [(CH3)2TcO2]2 (3). 5 is not isomorphous with {(CH3)3SnOReO3}n (6), the trimethylstannyl perrhenate, though both compounds have a zickzack chaine structure. 5 is monoclinic (C2h5-P21/c) with a = 961.6(9), b = 764.5(6), c = 1190.1(7) pm, β = 91.16(7)0, Z = 4, V = 874.71 x 106 pm3, droe = 2.48 g/cm3. While 6 possesses a crystallographic mirror plane 5 does not. (orig.)

Additional details

Additional titles

Original title (German)
Darstellung und Roentgenstrukturanalyse des polymeren Trimethylstannylpertechnetats, {(CH

Publishing Information

Journal Title
Zeitschrift fuer Naturforschung, B: Chemical Sciences
Journal Volume
46
Journal Issue
1
Series
Z. Naturforsch., B: Chem. Sci.
Journal Page Range
15-18
ISSN
0932-0776
CODEN
ZNBSE