Published November 2010 | Version v1
Journal article Metadata-only

Defects formation under photolysis of crystalline alkali nitrates

Creators

  • 1. Department of Analytical Chemistry, Kemerovo State University, Krasnaya str.6, 650043, Kemerovo (Russian Federation)

Description

The values of initial quantum yield of nitrite under photolysis (253.7 nm) of crystalline RbNO3 and CsNO3 were calculated to be 0.006 and 0.016 quantum-1, respectively. Thermal annealing of UV-irradiated samples result in 3-fold decrease in the nitrite quantum yield for RbNO3 and its 1.5-fold increase for CsNO3. The mechanism for nitrite formation under photolysis of crystalline alkali nitrates has been discussed.

Availability note (English)

Available from http://dx.doi.org/10.1088/1757-899X/15/1/012078

Additional details

Identifiers

DOI
10.1088/1757-899X/15/1/012078;

Publishing Information

Journal Title
IOP Conference Series. Materials Science and Engineering (Online)
Journal Volume
15
Journal Issue
1
Journal Page Range
[4 p.]
ISSN
1757-899X

Conference

Title
11. Europhysical Conference on Defects in Insulating Materials
Acronym
EURODIM 2010
Dates
12-16 Jul 2010
Place
Pecs (Hungary)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
43019249
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ANNEALING; CESIUM NITRATES; DEFECTS; NITRITES; PHOTOLYSIS; REACTION KINETICS; RUBIDIUM NITRATES
Descriptors DEC
ALKALI METAL COMPOUNDS; CESIUM COMPOUNDS; CHEMICAL REACTIONS; DECOMPOSITION; HEAT TREATMENTS; KINETICS; NITRATES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHOTOCHEMICAL REACTIONS; RUBIDIUM COMPOUNDS