Published November 1996
| Version v1
Journal article
Prediction of spur overlap time, radical yield profiles, and decomposition of trichloroethylene induced by various pulse types of electron beam
Creators
- 1. Samsung Engineering Co. Ltd., Kyunggi-Do (Korea, Republic of)
- 2. Korea Advanced Inst. of Science and technology, Taejon (Korea, Republic of). Dept. of Chemical Engineering
Description
A kinetic model was suggested to compute the yield profiles of primary radicals generated from water radiolysis. For various cases including pulse radiolysis and steady irradiation time of spur overlap was computed in order to ensure homogeneity over the entire system. As a result, consistency to roughly first order kinetics was resulted for decomposition of 1 ppm trichloroethylene (TCE) and slight deviation from the linear model was predicted for 10 ppm TCE. (author)
Additional details
Publishing Information
- Journal Title
- Radiation Physics and Chemistry (1993)
- Journal Volume
- 48
- Journal Issue
- 5
- Journal Page Range
- p. 651-657.
- ISSN
- 0969-806X
- CODEN
- RPCHDM
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 28007011
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; CHLORINATED ALIPHATIC HYDROCARBONS; COMPUTER CALCULATIONS; ELECTRON BEAMS; MATHEMATICAL MODELS; PULSED IRRADIATION; RADICALS; RADIOLYSIS; SCAVENGING
- Descriptors DEC
- BEAMS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; DISPERSIONS; HALOGENATED ALIPHATIC HYDROCARBONS; HOMOGENEOUS MIXTURES; IRRADIATION; KINETICS; LEPTON BEAMS; MIXTURES; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; PARTICLE BEAMS; RADIATION EFFECTS; REACTION KINETICS; SOLUTIONS