Published September 2017 | Version v1
Journal article Metadata-only

Structure of complexes of uranyl succinate with carbamide and dimethylurea

Creators

  • 1. Samara National Research University (Russian Federation)
  • 2. Russian Academy of Sciences, Frumkin Institute of Physical Chemistry and Electrochemistry (Russian Federation)

Description

Three new succinate-containing complexes of uranyl with carbamide (Urea) and N,N'-dimethylurea (s-Dmur) are synthesized and studied by IR spectroscopy and X-ray diffraction. Structures of the same type, [UO2(Urea)4(H2O)][(UO2)2(C4H4O4)3] · 3H2О and [UO2(Urea)4(H2O)][(UO2)2(C4H4O4)3] · 2Urea contain two sorts of uranium-containing complex groups, namely, mononuclear [UO2(Urea)4(H2O)]2+ cations and two-dimensional [(UO2)2(C4H4O4)3]2– anions described by crystal-chemical formulas A#041C#51 and A2Q302, respectively (A = UO22+, M1 = Urea or H2O, Q02 = C4H4O42-), and differ only in the nature of noncoordinated molecules—water and carbamide. The main structural groups of the [(UO2)2(C4H4O4)2(s-Dmur)3] crystals are [(UO2)2(C4H4O4)2(s-Dmur)3] chains belonging to the #0410#2Q202M31 (A = UO22+, Q02 = C4H4O42-, M1 = s-Dmur) crystal-chemical group. Specific features of intermolecular interactions in the crystal structures are revealed using the Voronoi–Dirichlet method of molecular polyhedra.

Additional details

Identifiers

DOI
10.1134/S1063774517040204;

Publishing Information

Journal Title
Crystallography Reports
Journal Volume
62
Journal Issue
5
Journal Page Range
p. 716-724
ISSN
1063-7745
CODEN
CYSTE3

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
50001212
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ANIONS; CATIONS; CRYSTALS; DIRICHLET PROBLEM; INFRARED SPECTRA; MOLECULES; TWO-DIMENSIONAL SYSTEMS; URANIUM; URANIUM COMPLEXES; URANIUM DIOXIDE; UREA; WATER; X-RAY DIFFRACTION
Descriptors DEC
ACTINIDE COMPLEXES; ACTINIDE COMPOUNDS; ACTINIDES; AMIDES; BOUNDARY-VALUE PROBLEMS; CARBONIC ACID DERIVATIVES; CHALCOGENIDES; CHARGED PARTICLES; COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; ELEMENTS; HYDROGEN COMPOUNDS; IONS; METALS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; SCATTERING; SPECTRA; URANIUM COMPOUNDS; URANIUM OXIDES

Optional Information

Copyright
Copyright (c) 2017 Pleiades Publishing, Inc.