Published December 2003 | Version v1
Journal article Metadata-only

Synthesis and crystal structure of heptakis(dimethyl sulfoxide)nitratolanthanum(III) tetraiodomercurate(II)

Creators

  • 1. Kuzbasskij Gosudarstvennyj Tekhnicheskij Univ., Kemerovo (Russian Federation)

Description

A new complex heptakis(dimethyl sulfoxide)nitratolanthanum(III) tetraiodomercurate(II) [La(DMSO)7(NO3)][HgI4] (DMSO=dimethyl sulfoxide) was synthesized and studied by X-ray diffraction. The crystallographic data are: a=17.823(3) A, b=13.898(2) A, c=18.971(3) A, β=112.37(1) Deg, Z=4, space groups P21/c. The crystals are built of complex [HgI4]2- anions and [La(DMSO)7(NO3)]2+ cations

Abstract (Russian)

Синтезирован новый комплекс - тетраиодомеркурат(II) нитрогептадиметилсульфоксидлантана(III) [La(DMSO)7(NO3)][HgI4] (DMSO=диметилсульфоксид) и проведено рентгеноструктурное исследование. Кристаллографические данные: a=17.823(3) A, b=13.898(2) A, c=18.971(3) A, β=112.37(1) град., Z=4, пр. гр. P21/c. Кристаллы построены из комплексных анионов [HgI4]2- и катионов [La(DMSO)7(NO3)]2+

Additional details

Additional titles

Original title (Russian)
Sintez i kristallicheskaya struktura tetraiodomerkurata(II) nitrogeptadimetilsul'foksidlantana(III)

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
48
Journal Issue
12
Journal Page Range
p. 2039-2042
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36055106
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; CHEMICAL PREPARATION; COORDINATION NUMBER; DMSO; IODIDES; LANTHANUM COMPLEXES; LATTICE PARAMETERS; MERCURY COMPLEXES; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; NITRATES
Descriptors DEC
COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIMENSIONS; HALIDES; HALOGEN COMPOUNDS; IODINE COMPOUNDS; LENGTH; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; RARE EARTH COMPLEXES; SULFOXIDES; SYNTHESIS

Optional Information

Notes
9 refs.; 2 tabs.; 2 figs.