Gamma radiation effects on the polymers used as ion exchange resin imobilizers: Part I - properties of the low density polyethylene (LDPE)

In this work tests were realized to evaluate properties such as: density, Shore D hardness, tensile strength and rupture elongation of low density polyethylene (LDPE), which is used as resin solidification agent, in function of irradiation dose and ion exchange resin concentration incorporated. It also was observed LDPE color change, due to interaction between polymer and gamma radiation. The results showed the occurrence of phenyl radical formation, deriving from amine aromatic additive, introduced by polymer producer, which is responsible by color change. Up to studied dose of 5 MGy, the aromatic chain presence gave to LDPE the good resistance to radiation. Resin concentration provoked more variation on properties than radiation effect. It was possible to incorporate up to 60% wt of resin, resulting high reduction of final volume. (author)