Published March 1997
| Version v1
Journal article
Regenerative mechanism of activation of chemiluminescence from the reaction of diethoxyethylaluminium with xenon difluoride
- 1. Inst. Organicheskoj Khimii Ufimskogo Nauchnogo Tsentra RAN, Ufa (Russian Federation)
Description
The effect of luminescence activator (A) - [Ru(bipy)3Cl2 · (AOC)n] (AOC - organic aluminium compound) on chemiluminescence in the reaction of diethoxyethyl aluminium (EtO)2AlEt with xenon difluoride in solution is studied. It is shown that the growth of luminescence takes place in the result of activator participation in redox processes. It is established that excitation of A molecules or Ru(2+) complex occurs on the stage of reduction of oxidized form of activator by AOC. (author)
Additional details
Additional titles
- Original title (Russian)
- Регенеративный механизм активации хемилюминесценции в реакции диэтоксиэтилалюминия с дифторидом ксенона
Publishing Information
- Journal Title
- Khimiya Vysokikh Ehnergij
- Journal Volume
- 31
- Journal Issue
- 2
- Journal Page Range
- p. 133-136.
- ISSN
- 0023-1193
- CODEN
- KHVKAO
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 28071052
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALUMINIUM COMPOUNDS; BIPYRIDINES; CHEMICAL REACTION KINETICS; CHEMILUMINESCENCE; CHLORIDES; ORGANOMETALLIC COMPOUNDS; REACTION INTERMEDIATES; RUTHENIUM COMPLEXES; SOLUTIONS; XENON FLUORIDES
- Descriptors DEC
- AZINES; CHLORINE COMPOUNDS; COMPLEXES; DISPERSIONS; EMISSION; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; HOMOGENEOUS MIXTURES; KINETICS; LUMINESCENCE; MIXTURES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHOTON EMISSION; PYRIDINES; RARE GAS COMPOUNDS; REACTION KINETICS; TRANSITION ELEMENT COMPLEXES; XENON COMPOUNDS
Optional Information
- Notes
- 12 refs., 4 figs.