The extrinsic origin of the magnetodielectric effect in the double perovskite La2NiMnO6

A La2NiMnO6 polycrystalline sample prepared by the sol-gel method showed monoclinic crystal structure with the P21/n space group and a saturation magnetization of 4.63 μB/f.u. at 5 K. Impedance spectroscopy results in the temperature range of 10 K < T < 300 K have revealed a distinct conduction process at grains and grain boundaries, where the grains followed the variable range hopping mechanism and the grain boundaries obeyed Arrhenius thermal activation. A negative magnetoresistance of 2.5% was observed at the paramagnetic to ferromagnetic transition, and this became temperature independent below the magnetic ordering. A marginal positive magnetodielectric (MD) effect that followed the dielectric relaxation was observed and its magnitude was found to decrease with increase of the frequency. A systematic study on the magnetic field induced dielectric properties, dc transport and dc bias effect on the dielectric permittivity has revealed the extrinsic origin of the MD effect in the bulk sample of La2NiMnO6.