Published October 1999
| Version v1
Journal article
A new series of Ru(II) polypyridine surfactants: synthesis, 2D NMR, fluorescence, electrochemistry and electrochemiluminescence
Creators
- 1. National Analytical Research Center of Electrochemistry and Spectroscopy, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchum (China)
Description
A new series of Ru(II) polypyridine surfactants, Ru(bpy)2[phenNHCO (CH2))nCH3](PF6)2, where n is 10, 12, 14 or 16, has been prepared and characterized. The 1H-NMR spectra of these new Ru(II) complexes were attributed and discussed by the 1H-1H COSY method. The comparative analysis of IR spectra of these complexes and their responding free ligands has shown that there are intensive d-> π* feedback interactions between central Ru(II) and their ligands. Their fluorescent, electrochemical and electrochemiluminescent behaviours are also reported. (author)
Additional details
Publishing Information
- Journal Title
- Asian Journal of Chemistry
- Journal Volume
- 11
- Journal Issue
- 4
- Journal Page Range
- p. 1307-1312
- CODEN
- AJCHEW
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 30056520
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ELECTROLUMINESCENCE; FLUORESCENCE; INFRARED SPECTRA; LIGANDS; NMR SPECTRA; PYRIDINES; RUTHENIUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; SURFACTANTS
- Descriptors DEC
- AZINES; COMPLEXES; EMISSION; HETEROCYCLIC COMPOUNDS; LUMINESCENCE; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHOTON EMISSION; SPECTRA; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- 9 refs., 4 figs., 2 tabs.