Published January 1984 | Version v1
Journal article Metadata-only

Term dependent correlation crystal field to the 2H(2) sub(11/2) levels of Nd+3:LiYF4

Creators

  • 1. Pernambuco Univ., Recife (Brazil). Dept. de Quimica Fundamental e Dept. de Fisica

Description

Phenomenological crystal field parameters reproduce quite satisfactorily the splittings of a very large number of levels of Nd3+ : LiYF4 but give less than half the observed splitting of the 2H(2) sub(11/2) multiplet. Phenomenological two-body crystal field parameters were able to account for more than 50% of this discrepancy. (C.L.B.)

Abstract (Portuguese)

Parametros fenomenologicos de campo cristalino reproduzem satisfatoriamente as separacoes de um grande numero de niveis no sistema Nd3+ : LiYF4 mas fornecem menos da metade das separacoes do multiplete de 2H(2) sub(11/2). Parametros fenomenologicos de campo cristalino de dois corpos foram capazes de explicar mais do que 50% dessa discrepancia. (C.L.B.)

Additional details

Publishing Information

Journal Title
Quim. Nova
Journal Volume
7
Journal Issue
1
Series
Quim. Nova.
Journal Page Range
49-50
ISSN
0100-4042

INIS

Country of Publication
Brazil
Country of Input or Organization
Brazil
INIS RN
15066407
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CRYSTAL FIELD; EQUATIONS; RARE EARTH COMPOUNDS; TRANSITION ELEMENT COMPOUNDS