Published December 2019 | Version v1
Journal article

Comment on "Fourier transform of hydrogen-type atomic orbitals"

Creators

  • 1. Universitaet Regensburg, Institute fuer Physikalische und Theoretische Chemie, Regensburg (Germany)

Description

Podolsky and Pauling (Phys. Rev. 34, 109 (1929) doi:10.1103/PhysRev.34.109) were the first ones to derive an explicit expression for the Fourier transform of a bound-state hydrogen eigenfunction. Yukcu and Yukcu (Can. J. Phys. 96, 724 (2018) doi:10.1139/cjp-2017-0728), who were apparently unaware of the work of Podolsky and Pauling or of the numerous other earlier references on this Fourier transform, proceeded differently. They expressed a generalized Laguerre polynomial as a finite sum of powers, or equivalently, they expressed a bound-state hydrogen eigenfunction as a finite sum of Slater-type functions. This approach looks very simple, but it leads to comparatively complicated expressions that cannot match the simplicity of the classic result obtained by Podolsky and Pauling. It is, however, possible to reproduce not only Podolsky and Pauling's formula for the bound-state hydrogen eigenfunction, but to obtain results of similar quality also for the Fourier transforms of other, closely related, functions, such as Sturmians, Lambda functions, or Guseinov's functions, by expanding generalized Laguerre polynomials in terms of so-called reduced Bessel functions. (author)

Availability note (English)

Available from doi: https://doi.org/10.1139/cjp-2019-0046

Additional details

Identifiers

Publishing Information

Journal Title
Canadian Journal of Physics
Journal Volume
97
Journal Issue
12
Journal Page Range
p. 1349-1360
ISSN
0008-4204

INIS

Country of Publication
Canada
Country of Input or Organization
Canada
INIS RN
52022408
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
Descriptors DEI
BOUND STATE; EIGENFUNCTIONS; FOURIER TRANSFORMATION; HYDROGEN; SLATER METHOD
Descriptors DEC
CALCULATION METHODS; ELEMENTS; FUNCTIONS; INTEGRAL TRANSFORMATIONS; NONMETALS; TRANSFORMATIONS

Optional Information

Notes
89 refs.