Published July 1988 | Version v1
Journal article Metadata-only

Radiation telomerization of ethylene by 3-methylbutanoic acid

Creators

  • 1. Moskovskij Khimiko-Tekhnologicheskij Inst. (USSR)

Description

γ-radiation telomerization of ethylene by 3-methylbutanoic acid is performed. The composition of reaction products is determined. The presence of only one series of telomeric products formed, when the α-CH bond in the acid is broken, is shown. The effect of the concentration relation of initial reagents and temperature (50-150 deg C) on radiation-chemical yield of telomeric acids is studied. The activation energy of addition of radicals produced during acid radiolysios to ethylene is determined. The particular constants of chain propagation are calculated

Additional details

Additional titles

Original title (Russian)
Радиационная теломеризация этилена 3-метилбутановой кислотой

Publishing Information

Journal Title
Khimiya Vysokikh Ehnergij
Journal Volume
22
Journal Issue
4
Series
Khim. Vys. Ehnerg.
Journal Page Range
326-328
ISSN
0023-1193
CODEN
KHVKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
20011038
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ACTIVATION ENERGY; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTION KINETICS; ETHYLENE; G VALUE; GAMMA RADIATION; HIGH TEMPERATURE; ISOVALERIC ACID; MEDIUM TEMPERATURE; QUANTITY RATIO; TELOMERIZATION; TEMPERATURE DEPENDENCE
Descriptors DEC
ALKENES; CARBOXYLIC ACIDS; CHEMICAL REACTIONS; ELECTROMAGNETIC RADIATION; ENERGY; HYDROCARBONS; IONIZING RADIATIONS; KINETICS; MONOCARBOXYLIC ACIDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; POLYMERIZATION; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS