Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
Creators
- 1. Departamento de Química, Universidade Federal de Goiás, 75704-020, Catalão, GO (Brazil)
- 2. Departamento de Física, Universidade Federal de São Carlos, São Carlos, São Paulo, 13565-905 (Brazil)
- 3. Departamento de Engenharia de Materiais, Universidade Federal do Rio Grande do Norte, Natal, RN (Brazil)
Description
Forms of degradation of the environmental pollutant sulphamethoxazole have been studied over the years, and one form of degradation in heterogeneous photocatalysis. In this work a study was carried out to elaborate a photocatalyst capable of degrading the pollutant sulfamethoxazole, starting to elaborate heterojunctions between TiO2 and CeO2 doped with gadolinium, showing that the combination of both materials is able to contribute to the degradation of the pollutant, promoting 97% degradation. This favorable performance can be attributed by the formation of a characterized heterojunction with presence of mesopores that aid in the adsorption processes on the surface of the photocatalyst, and a high formation of active sites resulting from the formation of the electron pair, promoted by the excitation of the electrons of the band of valence for conduction band by means of photons.
Additional details
Identifiers
- DOI
- 10.1016/j.jallcom.2019.151711;
- PII
- S0925838819329445;
Publishing Information
- Journal Title
- Journal of Alloys and Compounds
- Journal Volume
- 808
- Journal Page Range
- vp.
- ISSN
- 0925-8388
- CODEN
- JALCEU
INIS
- Country of Publication
- Switzerland
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 55049709
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- ADSORPTION; CERIUM OXIDES; DOPED MATERIALS; ELECTRONS; GADOLINIUM; HETEROJUNCTIONS; PERFORMANCE; PHOTOCATALYSIS; PHOTONS; SURFACES; TITANIUM OXIDES; VALENCE
- Descriptors DEC
- BOSONS; CATALYSIS; CERIUM COMPOUNDS; CHALCOGENIDES; ELEMENTARY PARTICLES; ELEMENTS; FERMIONS; LEPTONS; MASSLESS PARTICLES; MATERIALS; METALS; OXIDES; OXYGEN COMPOUNDS; RARE EARTH COMPOUNDS; RARE EARTHS; SEMICONDUCTOR JUNCTIONS; SORPTION; TITANIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2019 Elsevier B.V. All rights reserved.