Published November 2007 | Version v1
Journal article Metadata-only

Crown-substituted Sc(III) phthalocyaninates: synthesis and spectral properties

Creators

  • 1. RAN, Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova, Moscow (Russian Federation)
  • 2. RAN, Inst. Fiziko-Khimicheskikh Problem Keramicheskikh Materialov, Moscow (Russian Federation)
  • 3. Inst. Fizicheskoj Khimii i Ehlektrokhimii im. A.N. Frumkina, Moscow (Russian Federation)

Description

The scandium(III) complexes with tetra(15-crown-5)phthalocyanine [Sc(R4Pc)2].0 (I) and Sc(R4Pc) · OAc (II) have been synthesized by condensation of Sc3+ with phthalocyanine H2R4Pc (4, 5, 4',5',4'',5'',4''',5'''-tetrakis(1, 4, 7, 10, 13-pentaoxatridecamethylene)phthalocyanine). Compounds I and II have been characterized by spectral methods: electronic absorption spectroscopy, MALDI-TOF MS, IR spectroscopy, and 1H NMR. The redox properties of I and the photoluminescence properties of II have been studied

Abstract (Russian)

Синтезированы комплексы Sc(III) с тетра(15-краун-5)фталоцианином составов [Sc(R4Pc)2].0 (I) и Sc(R4Pc) · ОАс (II) методом конденсации Sc3+ с фталоцианином, H2R4Pc (4, 5, 4', 5', 4'', 5'',4''', 5'''-тетракис (1, 4, 7, 10, 13 - пентаоксатридекаметилен)фталоцианин). Соединения I и II охарактеризованы спектральными методами: ЭСП, MALDI-TOF-MS, ИК, ЯМР 1H. Изучены окислительно-восстановительные свойства I, а также фотолюминесцентные свойства II

Additional details

Additional titles

Original title (Russian)
Краун-замещенные фталоцианинаты Сc(III): синтез и спектральные свойства

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
52
Journal Issue
11
Journal Page Range
p. 1868-1878
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
39078849
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; ACETATES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CROWN ETHERS; INFRARED SPECTRA; MASS SPECTRA; MOLECULAR STRUCTURE; NMR SPECTRA; PHOTOLUMINESCENCE; PHTHALOCYANINES; PROTONS; REDOX REACTIONS; SCANDIUM COMPLEXES; SOLUTIONS
Descriptors DEC
BARYONS; CARBOXYLIC ACID SALTS; CHEMICAL REACTIONS; COMPLEXES; DISPERSIONS; DYES; ELEMENTARY PARTICLES; EMISSION; ETHERS; FERMIONS; HADRONS; HETEROCYCLIC COMPOUNDS; HOMOGENEOUS MIXTURES; LUMINESCENCE; MIXTURES; NUCLEONS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PHOTON EMISSION; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; YIELDS

Optional Information

Notes
21 refs., 5 figs., 2 tabs.