Published 1981 | Version v1
Journal article

Application of inversion amalgam chronopotentiometry to study formation of mixed citrate-chloride complexes of cadmium (2)

  • 1. Tyumenskij Industrial'nyj Inst. (USSR)

Description

Existence of mixed citrate-chloride complexes of cadmium CdClCit2-, CdCl2Cit3-, CdClCit25- is established according to the results of the study of the Cd2+ - Cit3- - Cl- system using the method of amalgam chronopotentiometry at 25 deg C against the background of sodium perchlorate with ion force 4. Stability constants of the complexes formed are calculated. Conclusions are made on the absence of noticeable mutual effect of anions in the inner coordination sphere

Additional details

Additional titles

Original title (Russian)
Применение инверсионной амальгамной хронопотенциометрии для изучения образования смешанных цитратно-хлоридных комплексов кадмия (2)

Publishing Information

Journal Title
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol.
Journal Volume
24
Journal Issue
9
Series
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol.
Journal Page Range
1063-1066
ISSN
0579-2991

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
13704992
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CADMIUM COMPLEXES; CHEMICAL PREPARATION; CHLORIDES; CITRATES; POLAROGRAPHY; STABILITY
Descriptors DEC
CARBOXYLIC ACID SALTS; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; SYNTHESIS