Published November 1986
| Version v1
Journal article
Triplet states of cyclic olefins and dienes
- 1. Osaka Univ., Ibaraki (Japan). Inst. of Scientific and Industrial Research
Description
Triplet lifetimes of cyclic olefins and dienes measured by pulse radiolysis are dependent on the ring size which affects the most stable conformation of the triplet. In the case of cyclic nonconjugated dienes, an intramolecular biradical formation is an important decay process when the reaction is sterically allowed. (author)
Additional details
Additional titles
- Subtitle (English)
- On the lifetimes and chemical reactivities studied by pulse radiolysis
Publishing Information
- Journal Title
- Chem. Lett. (Tokyo)
- Journal Volume
- 1986
- Journal Issue
- 11
- Series
- Chem. Lett. (Tokyo).
- Journal Page Range
- 1889-1892
- ISSN
- 0366-7022
- CODEN
- CMLTA
INIS
- Country of Publication
- Japan
- Country of Input or Organization
- Japan
- INIS RN
- 18082080
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; ALKENES; CHEMICAL REACTION KINETICS; CYCLOALKENES; LIFETIME; PULSE TECHNIQUES; RADIOLYSIS; RINGS; TRIPLETS
- Descriptors DEC
- CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; HYDROCARBONS; KINETICS; MULTIPLETS; ORGANIC COMPOUNDS; RADIATION EFFECTS; REACTION KINETICS; SPECTRA