Published December 1988 | Version v1
Journal article

Calculated rotational and rovibrational transitions in the spectrum of H3(+)

  • 1. University College, London (England)

Description

New calculations of line strengths and transition frequencies for the forbidden rotational spectrum and the nu2 fundamental rovibrational band of H3(+) are presented. These first principles calculations use the highly accurate ab initio electronic potential energy surface of Meyer, Botschwina, and Burton (1986), which has previously been shown by the authors to give rovibrational transition frequencies, rotational constants and vibrational fundamentals of spectroscopic accuracy. The line strengths calculated for the pure rotational spectrum in the vibrational ground state are in general agreement with those previously predicted by Pan and Oka (1986), although individual line strengths may differ by as much as 50 percent. The data are presented to assist with the interstellar detection of this astrophysically important molecular ion. 25 references

Additional details

Publishing Information

Journal Title
Astrophysical Journal
Journal Volume
335
Series
Astrophys. J.
Journal Page Range
486-490
ISSN
0004-637X
CODEN
ASJOA

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
20031653
Subject category
S79: ASTROPHYSICS, COSMOLOGY AND ASTRONOMY;
Descriptors DEI
ANGULAR MOMENTUM; CHEMICAL COMPOSITION; DETECTION; ENERGY LEVELS; FORBIDDEN TRANSITIONS; HYDROGEN; INTERSTELLAR SPACE; MOLECULAR IONS; ROTATION; SPECTRA
Descriptors DEC
CHARGED PARTICLES; ELEMENTS; ENERGY-LEVEL TRANSITIONS; IONS; NONMETALS; SPACE