Analyses of significant features of L-Prolinium Picrate single crystal: An excellent material for non linear optical applications
Creators
- 1. CSIR-National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi, 110 012 (India)
- 2. Academy of Scientific and Innovative Research, CSIR- National Physical Laboratory, New Delhi, 110012 (India)
- 3. Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, 140001, Punjab (India)
- 4. Centro De Investigations En Optica, Loma del Bosque 115, Colonia Lomas del Campestre, León, Guanajuato, Código Postal, 37150 (Mexico)
- 5. International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala, 686560 (India)
- 6. Department of Physics and Electronics, University of Jammu, Jammu Tawi, 180006 (India)
Description
Today the fundamental aspect of the researchers is to explore maximum physical properties of the material for device fabrication. In the present article, single crystal X-ray diffraction has been carried out to verify the formation of the synthesized compound. In addition to that, powder X-ray diffraction has been performed to obtain diffraction pattern of L-Prolinium Picrate single crystal. The strain present inside the single crystal was measured using Hall-Williamson equation from PXRD measurements. The dark current and photon current was obtained from photoconductivity technique whose plot depicted that the sample was negative photoconducting material. Optical homogeneity of the single crystal was analyzed using birefringence technique. Its resistance towards Nd: YAG laser was scrutinized for L-Prolinium Picrate single crystal by applying 1 pulse per second. Different thermal parameters like thermal conductivity, thermal diffusivity, thermal effusivity and specific heat were computed using photo-pyroelectric technique. Solid state parameters were calculated from Clausius Mossotti relation by taking structural information of the title compound. Also, optical parameters like refractive index, reflectance etc were calculated through UV–Vis–NIR analysis. - Highlights: • An optically transparent L-Prolinium Picrate single crystal was harvested from slow evaporation solution growth technique. • The compound shows negative photoconducting nature. • Its optical homogeneity was analyzed using birefringence. • Single shot of laser was applied to sample to measure laser damage threshold value. • The thermal parameters were computed from Photopyroelectric technique.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.matchemphys.2017.02.028Additional details
Identifiers
- DOI
- 10.1016/j.matchemphys.2017.02.028;
- PII
- S0254-0584(17)30169-4;
Publishing Information
- Journal Title
- Materials Chemistry and Physics
- Journal Volume
- 194
- Journal Page Range
- p. 90-96
- ISSN
- 0254-0584
- CODEN
- MCHPDR
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 48073855
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- BIREFRINGENCE; DARK CURRENT; EVAPORATION; LASER MATERIALS; MONOCRYSTALS; NEODYMIUM LASERS; NONLINEAR OPTICS; PHOTOCONDUCTIVITY; PHOTONS; POWDERS; REFRACTIVE INDEX; SOLIDS; SPECIFIC HEAT; THERMAL CONDUCTIVITY; THERMAL DIFFUSIVITY; X-RAY DIFFRACTION
- Descriptors DEC
- BOSONS; COHERENT SCATTERING; CRYSTALS; CURRENTS; DIFFRACTION; ELECTRIC CONDUCTIVITY; ELECTRIC CURRENTS; ELECTRICAL PROPERTIES; ELEMENTARY PARTICLES; LASERS; LEAKAGE CURRENT; MASSLESS PARTICLES; MATERIALS; OPTICAL PROPERTIES; OPTICS; PHASE TRANSFORMATIONS; PHYSICAL PROPERTIES; REFRACTION; SCATTERING; SOLID STATE LASERS; THERMODYNAMIC PROPERTIES
Optional Information
- Copyright
- Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.