Published June 15, 2017 | Version v1
Journal article

Analyses of significant features of L-Prolinium Picrate single crystal: An excellent material for non linear optical applications

  • 1. CSIR-National Physical Laboratory, Dr. K.S. Krishnan Road, New Delhi, 110 012 (India)
  • 2. Academy of Scientific and Innovative Research, CSIR- National Physical Laboratory, New Delhi, 110012 (India)
  • 3. Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, 140001, Punjab (India)
  • 4. Centro De Investigations En Optica, Loma del Bosque 115, Colonia Lomas del Campestre, León, Guanajuato, Código Postal, 37150 (Mexico)
  • 5. International and Inter University Centre for Nanoscience and Nanotechnology, Mahatma Gandhi University, Kottayam, Kerala, 686560 (India)
  • 6. Department of Physics and Electronics, University of Jammu, Jammu Tawi, 180006 (India)

Description

Today the fundamental aspect of the researchers is to explore maximum physical properties of the material for device fabrication. In the present article, single crystal X-ray diffraction has been carried out to verify the formation of the synthesized compound. In addition to that, powder X-ray diffraction has been performed to obtain diffraction pattern of L-Prolinium Picrate single crystal. The strain present inside the single crystal was measured using Hall-Williamson equation from PXRD measurements. The dark current and photon current was obtained from photoconductivity technique whose plot depicted that the sample was negative photoconducting material. Optical homogeneity of the single crystal was analyzed using birefringence technique. Its resistance towards Nd: YAG laser was scrutinized for L-Prolinium Picrate single crystal by applying 1 pulse per second. Different thermal parameters like thermal conductivity, thermal diffusivity, thermal effusivity and specific heat were computed using photo-pyroelectric technique. Solid state parameters were calculated from Clausius Mossotti relation by taking structural information of the title compound. Also, optical parameters like refractive index, reflectance etc were calculated through UV–Vis–NIR analysis. - Highlights: • An optically transparent L-Prolinium Picrate single crystal was harvested from slow evaporation solution growth technique. • The compound shows negative photoconducting nature. • Its optical homogeneity was analyzed using birefringence. • Single shot of laser was applied to sample to measure laser damage threshold value. • The thermal parameters were computed from Photopyroelectric technique.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.matchemphys.2017.02.028

Additional details

Identifiers

DOI
10.1016/j.matchemphys.2017.02.028;
PII
S0254-0584(17)30169-4;

Publishing Information

Journal Title
Materials Chemistry and Physics
Journal Volume
194
Journal Page Range
p. 90-96
ISSN
0254-0584
CODEN
MCHPDR

Optional Information

Copyright
Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.