Published July 1990
| Version v1
Journal article
Tungsten (6) perchlorate compounds
Creators
- 1. AN SSSR, Moscow (USSR). Inst. Obshchej i Neorganicheskoj Khimii
Description
By interaction of WCl6 with anhydrous perchloric acid at -5 deg C WO(ClO4)4 has been prepared. In vacuum tungsten oxyperchlorate at 20 deg C loses Cl2O7 with formation of WO2(ClO4)2 (1), which at the temperature exceeding 90 deg C transforms into WO3 and loses the second molecule of perchloric anhydride. By means of interaction between 1 and MClO4 (M=Cs, Rb) in the medium of HClO4 cesium and rubidium dioxyperchloratotungstates of the general formula Mn(WO2(ClO4)2+n), where n=1, 2 have been prepared. By IR diffraction analysis it is ascertained that in 1 ClP4 groups are bidentate and in complex anions both bi- and monodentate perchloratogroups are present
Additional details
Additional titles
- Original title (Russian)
- Перхлоратные соединения вольфрама(VI)
Publishing Information
- Journal Title
- Zhurnal Neorganicheskoj Khimii
- Journal Volume
- 35
- Journal Issue
- 7
- Series
- Zh. Neorg. Khim.
- Journal Page Range
- 1659-1663
- ISSN
- 0044-457X
- CODEN
- ZNOKA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 22041719
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CESIUM COMPOUNDS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; HYDRATES; INFRARED SPECTRA; LATTICE PARAMETERS; MEDIUM TEMPERATURE; MOLECULAR STRUCTURE; PERCHLORATES; PYROLYSIS; RUBIDIUM COMPOUNDS; STABILITY; TUNGSTEN COMPLEXES; TUNGSTEN COMPOUNDS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; DECOMPOSITION; HALOGEN COMPOUNDS; OXYGEN COMPOUNDS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS