Published June 1989
| Version v1
Journal article
The Pentaborate Ba2LiB5O10
Description
The structure of the compound Ba2LiB5O10 has been established by single-crystal X-ray methods. It crystallizes in the monoclinic space group P21/m in a cell of dimensions a = 4.414(1), b = 14.576(2), c = 6.697(2) A* and β = 104.26(2)0 with Z = 2. Refinement from 2373 independent reflections affords the final residuals R = 0.021 and Rw = 0.042. The structure exhibits a unique one-dimensional polyborate anion built from two crystallographically independent BO3 groups and a distinct BO4 group that share vertices. The polyanions are bridged by a Li atom occupying a distorted tetrahedral site and a Ba atom occupying an irregular eightfold coordinate site
Additional details
Publishing Information
- Journal Title
- Materials Research Bulletin
- Journal Volume
- 24
- Journal Issue
- 6
- Series
- Mater. Res. Bull.
- Journal Page Range
- 725-731
- ISSN
- 0025-5408
- CODEN
- MRBUA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 21023125
- Subject category
- S36: MATERIALS SCIENCE; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ATOMS; BARIUM OXIDES; BORON OXIDES; CRYSTALLOGRAPHY; LITHIUM; LITHIUM OXIDES; MICROSTRUCTURE; MONOCRYSTALS; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ALKALI METALS; ALKALINE EARTH METAL COMPOUNDS; BARIUM COMPOUNDS; BORON COMPOUNDS; CHALCOGENIDES; COHERENT SCATTERING; CRYSTAL STRUCTURE; CRYSTALS; DIFFRACTION; ELEMENTS; LITHIUM COMPOUNDS; METALS; OXIDES; OXYGEN COMPOUNDS; SCATTERING