Published January 1, 2010 | Version v1
Journal article Metadata-only

High frequency ESR measurements on the spin crossover complex [MnIII(taa)]

Creators

  • 1. KYOKUGEN, Osaka University, Toyonaka, Osaka 560-8531 (Japan)
  • 2. Institute for Material Research, Tohoku University, Sendai 980-8577 (Japan)
  • 3. Graduate school of Engineering, Osaka University, Suita, Osaka 565-0871 (Japan)
  • 4. Institute for Solid State Physics, University of Tokyo, Kashiwa 277-8531 (Japan)

Description

We have performed ESR measurements on a single crystal of the spin crossover complex [MnIII(taa)]. Symmetry lowering due to the Jahn-Teller effect in the High spin state of [MnIII(taa)] is detected by the ESR measurements. From the analysis based on a spin Hamiltonian, we discuss the distortion in the molecular structure of [MnIII(taa)].

Availability note (English)

Available from http://dx.doi.org/10.1088/1742-6596/200/2/022025

Additional details

Identifiers

DOI
10.1088/1742-6596/200/2/022025;

Publishing Information

Journal Title
Journal of Physics. Conference Series (Online)
Journal Volume
200
Journal Issue
2
Journal Page Range
[4 p.]
ISSN
1742-6596

Conference

Title
international conference on magnetism
Acronym
ICM 2009
Dates
26-31 Jul 2009
Place
Karlsruhe (Germany)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
42041467
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ELECTRON SPIN RESONANCE; HAMILTONIANS; HIGH SPIN STATES; JAHN-TELLER EFFECT; MANGANESE COMPLEXES; MOLECULAR STRUCTURE; MONOCRYSTALS; SPIN; SYMMETRY
Descriptors DEC
ANGULAR MOMENTUM; COMPLEXES; CRYSTALS; ENERGY LEVELS; MAGNETIC RESONANCE; MATHEMATICAL OPERATORS; PARTICLE PROPERTIES; QUANTUM OPERATORS; RESONANCE; TRANSITION ELEMENT COMPLEXES