Published February 1999 | Version v1
Journal article

Preparation of polypropylene fabric adsorbent containing phosphoric acid by radiation-induced graft copolymerization, and adsorption of Cu2+, Pb2+ and Co2+

  • 1. Hannam Univ., Taejon (Korea, Republic of)
  • 2. KAERI, Taejon (Korea, Republic of)

Description

The cation-exchange adsorbent (CEA) was prepared by radiation-induced grafting of glycidyl methacrylate (GMA) onto polypropylene (PP) fabric and its subsequently phosphonation. The adsorption characteristics of Pb2+, Cu2+ and Co2+ for the CEA were discussed. In the grafting of GMA onto PP fabric, the degree of grafting (%) increased with increasing reaction time, reaction temperature, and pre-irradiation dose. The maximum grafting yield was observed around 60% GMA concentration. The content of phosphoric acid ranges from 2.5 to 3.5 mmol/g with the 85% phosphoric acid. The adsorption of Pb2+, Cu2+, Co2+ by the CEA was enhanced with increasing phosphoric acid content. The order of adsorption capacity of CEA was Pb2+>Co2+>Cu2+

Additional details

Publishing Information

Journal Title
Analytical Science and Technology
Journal Volume
12
Journal Issue
1
Series
17 refs, 8 figs
Journal Page Range
p. 7-12
ISSN
1225-0163

INIS

Country of Publication
Korea, Republic of
Country of Input or Organization
Korea, Republic of
INIS RN
34010166
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ADSORBENTS; CHEMICAL RADIATION EFFECTS; COPOLYMERIZATION; GRAFT POLYMERS; POLYPROPYLENE
Descriptors DEC
CHEMICAL REACTIONS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; POLYMERIZATION; POLYMERS; POLYOLEFINS; RADIATION EFFECTS