Published 2009 | Version v1
Journal article Metadata-only

Spruceanumines A and B, novel plumeran indole alkaloids from Aspidosperma spruceanum(Apocynaceae)

Creators

  • 1. Universidade Estadual do Norte Fluminense Darcy Ribeiro (UENF), Campos dos Goytacazes, RJ (Brazil). Lab. de Ciencias Quimicas (LCQUI)
  • 2. Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Faculdade de Ciencias Farmaceuticas
  • 3. Universidade de Franca, SP (Brazil). Nucleo de Pesquisas em Ciencias Exatas e Tecnologicas
  • 4. Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Dept. de Quimica Organica e Inorganica. Centro Nordestino de Aplicacao e Uso da Ressonancia Magnetica Nuclear

Description

Two novel indole alkaloids with plumeran skeleton, spruceanumines A (1) and B (2), and eight known indole alkaloids, aspidospermidine (3), demethoxypalosine (4), aspidocarpine (5), aspidolimine (6), fendlerine (7), aspidolimidine (8), obscurinervidine (9) and obscurinervine (10) were isolated from stem bark and seeds methanolic extracts of Aspidosperma spruceanum. Compounds structures were elucidated on the basis of spectroscopic data, mainly those obtained by 1H and 13C NMR (1D and 2D) and mass spectrometry. (author)

Availability note (English)

Available from http://www.scielo.br/pdf/jbchs/v20n4/v20n4a19.pdf

Additional details

Identifiers

URL
http://www.scielo.br/pdf/jbchs/v20n4/v20n4a19.pdf;

Publishing Information

Journal Title
Journal of the Brazilian Chemical Society
Journal Volume
20
Journal Issue
4
Journal Page Range
p. 753-759
ISSN
0103-5053
CODEN
JOCSET

INIS

Country of Publication
Brazil
Country of Input or Organization
Brazil
INIS RN
40086760
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKALOIDS; BARK; CARBON 13; HYDROGEN 1; INDOLES; MASS SPECTRA; MEDICINAL PLANTS; METHANOL; METHOXY RADICALS; NMR SPECTRA; PLANT STEMS; SEEDS; SPRUCES; STRUCTURAL CHEMICAL ANALYSIS
Descriptors DEC
ALCOHOLS; ALKOXY RADICALS; AROMATICS; AZAARENES; AZOLES; CARBON ISOTOPES; CONIFERS; EVEN-ODD NUCLEI; HETEROCYCLIC COMPOUNDS; HYDROGEN ISOTOPES; HYDROXY COMPOUNDS; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PINOPHYTA; PLANT TISSUES; PLANTS; PYRROLES; RADICALS; SPECTRA; STABLE ISOTOPES; TREES

Optional Information

Notes
21 refs., 13 figs., 1 tabs., 1 sch.