Published April 17, 1987 | Version v1
Journal article

Evaluation of thermodynamic data on zirconium and hafnium halides and oxyhalides by means of transport experiments

  • 1. Philips Forschungslaboratorium G.m.b.H., Aachen (Germany, F.R.)

Description

A consistent set of thermodynamic data for zirconium and hafnium halides, oxides and oxyhalides was achieved. It was found that formation enthalpies of gaseous compounds could be derived from solubility measurements together with theoretical estimations and a revision of literature data. Free energy functions were calculated employing statistical mechanics. Data for liquid and solid compounds were obtained via sublimation and vaporization data. Chemical equilibria of zirconium and hafnium with halogens are discussed. 51 refs.; 16 figs.; 14 tabs

Additional details

Publishing Information

Journal Title
Philips J. Res.
Journal Volume
42
Journal Issue
1
Series
Philips J. Res.
Journal Page Range
15-40
ISSN
0165-5817
CODEN
PHJRD

INIS

Country of Publication
Netherlands
Country of Input or Organization
Netherlands
INIS RN
19026818
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
EXPERIMENTAL DATA; FILAMENTS; FORMATION FREE ENTHALPY; FREE ENERGY; HAFNIUM COMPOUNDS; HALOGEN COMPOUNDS; THERMODYNAMIC PROPERTIES; ZIRCONIUM COMPOUNDS
Descriptors DEC
DATA; ENERGY; FREE ENTHALPY; INFORMATION; NUMERICAL DATA; PHYSICAL PROPERTIES; TRANSITION ELEMENT COMPOUNDS