A new path-integral representation of the T-matrix in potential scattering

We employ the method used by Barbashov and collaborators in Quantum Field Theory to derive a path-integral representation of the T-matrix in nonrelativistic potential scattering which is free of functional integration over fictitious variables as was necessary before. The resulting expression serves as a starting point for a variational approximation applied to high-energy scattering from a Gaussian potential. Good agreement with exact partial-wave calculations is found even at large scattering angles. A novel path-integral representation of the scattering length is obtained in the low-energy limit. -- Highlights: → We derive a new path-integral representation for the T-matrix in quantum scattering from a potential. → The method is based on a technique used by Barbashov and collaborators in Quantum Field Theory. → Unlike previous approaches no unphysical degrees of freedom in the path integral are needed. → The new representation is used for a variational approximation of the T-matrix at high energies. → A new expression for the scattering length at low energy is derived.