Published September 1993
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Mew organometallic complexes of technetium in different oxidation states
Description
New organometallic compounds of Tc(I), Tc(III) and Tc(VII) were synthesized and their properties examined. These compounds were correlated with their homologous compounds of manganese and rhenium, which were also synthesized by the same route. The molecular and crystal structures of most technetium complexes and of the homologous complexes of manganese and rhenium were determined by single crystal X-ray diffraction. (orig.)
Availability note (English)
MF available from INIS under the Report Number.Abstract (German)
Metallorganische Verbindungen des ein-, drei- und siebenwertigen Technetiums wurden synthetisiert, charakterisiert, ihre Eigenschaften untersucht und mit den auf analogen Reaktionswegen synthetisierten homologen Rhenium- und Manganverbindungen verglichen. Sowohl von den meisten Technetiumverbindungen als auch von den Mangan- und Rheniumhomologen (soweit noch nicht bekannt) konnten die Molekuel- und Kristallstrukturen durch Roentgenstrukturanalyse ermittelt werden. (orig.)
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Additional details
Additional titles
- Subtitle (English)
- Synthesis, properties and structures in correlation with the homologous compounds of manganese and rhenium
- Original title (German)
- Neue metallorganische Komplexe des Technetiums in diversen Oxidationsstufen
- Original subtitle (German)
- Synthesen, Eigenschaften und Strukturen im Vergleich mit Homologen des Mangans und Rheniums.
Publishing Information
- Imprint Pagination
- 193 p.
- ISSN
- 0303-4003
- Report number
- KFK--5239
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 25033200
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data, Thesis
- Descriptors DEI
- BOND ANGLE; BOND LENGTHS; CHEMICAL PREPARATION; CHEMICAL PROPERTIES; CRYSTAL STRUCTURE; EXPERIMENTAL DATA; MANGANESE COMPLEXES; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; RHENIUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; TECHNETIUM COMPLEXES; TECHNETIUM 99; VALENCE
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; COMPLEXES; DATA; HOURS LIVING RADIOISOTOPES; INFORMATION; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTOPES; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; NUCLEI; NUMERICAL DATA; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; RADIOISOTOPES; SYNTHESIS; TECHNETIUM ISOTOPES; TRANSITION ELEMENT COMPLEXES; YEARS LIVING RADIOISOTOPES