A critical review on the electrospun nanofibrous membranes for the adsorption of heavy metals in water treatment

Highlights: • Preparation of ENFMs and their adsorption for heavy metals in water are reviewed. • ENFMs are classified and adsorption capacities of different ENFMs are summarized. • Surface modification and organic/inorganic composite ENFMs are research hotspots. • Adsorption mechanism and influencing factor of ENFMs for heavy metal are discussed. • Current challenges, future research and application prospects are highlighted. Electrospun nanofibrous membranes (ENFMs) have many superior advantages, such as large specific surface area, high porosity, easy modification, good flexibility, and easy separation for recycling, which are consider as excellent adsorbents. In this paper, the research progress in the adsorption of heavy metals in water treatment by ENFMs is reviewed. Three types of ENFMs, including organic polymer ENFMs, organic polymer/inorganic material composite ENFMs and inorganic ENFMs are summarized, and their adsorption capacities for heavy metals in water are compared. The adsorption selectivity and capacity of ENFMs for heavy metals are depended largely on the type and number of functional groups on the surface of membranes, and usually the more the functional groups, the higher the adsorption capacity. The adsorption mechanisms of ENFMs are also mainly determined by the type of functional groups on the membrane. At present, the main challenge is to achieve the mass production of high-quality nanofibers and their actual application in the treatment of heavy metal-containing wastewater. Therefore, more consideration should be focused on the improvement of stability, mechanical strength and reusability of ENFMs. This review may provide an insight for the development of ENFMs-based adsorbents for heavy metals separation and water purification in the future.