Inclusion of electron correlation for the target wave function in low-energy e-+N2 scattering
Creators
- 1. Theoretische Chemie, Physikalisch Chemisches Institut, Universitaet Heidelberg, Im Neuenheimer Feld 253, W-6900 Heidelberg (Germany)
Description
The interaction of a scattering electron with a correlated but ''frozen'' target may be called the correlated static-exchange interaction. There are two prior investigations [J.R. Rumble, W.J. Stevens, and D. Truhlar, J. Phys. B 17, 3151 (1984); C Weatherford, F.B. Brown, and A. Temkin, Phys. Rev. A 35, 4561 (1987)] on scattering off the correlated static-exchange potential. Both of these investigations concentrated on e-+N2 scattering, and both have found that the correlated static-exchange potential is less attractive than the static-exchange potential. We will show, however, that the correlated static-exchange potential is more attractive than the static-exchange one---at least for e-+N2 scattering in 2Πg symmetry. The two prior investigations were misled by an improper degree of correlation and by an improper treatment of the exchange
Additional details
Publishing Information
- Journal Title
- Physical Review. A
- Journal Volume
- 46
- Journal Issue
- 1
- Journal Page Range
- p. 186-193.
- ISSN
- 1050-2947
- CODEN
- PLRAAN
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 24021098
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ELECTRON CORRELATION; ELECTRON-MOLECULE COLLISIONS; NITROGEN; POTENTIALS; RESONANCE; SCATTERING; WAVE FUNCTIONS
- Descriptors DEC
- COLLISIONS; CORRELATIONS; ELECTRON COLLISIONS; ELEMENTS; FUNCTIONS; MOLECULE COLLISIONS; NONMETALS