Published July 1, 1992 | Version v1
Journal article

Inclusion of electron correlation for the target wave function in low-energy e-+N2 scattering

  • 1. Theoretische Chemie, Physikalisch Chemisches Institut, Universitaet Heidelberg, Im Neuenheimer Feld 253, W-6900 Heidelberg (Germany)

Description

The interaction of a scattering electron with a correlated but ''frozen'' target may be called the correlated static-exchange interaction. There are two prior investigations [J.R. Rumble, W.J. Stevens, and D. Truhlar, J. Phys. B 17, 3151 (1984); C Weatherford, F.B. Brown, and A. Temkin, Phys. Rev. A 35, 4561 (1987)] on scattering off the correlated static-exchange potential. Both of these investigations concentrated on e-+N2 scattering, and both have found that the correlated static-exchange potential is less attractive than the static-exchange potential. We will show, however, that the correlated static-exchange potential is more attractive than the static-exchange one---at least for e-+N2 scattering in 2Πg symmetry. The two prior investigations were misled by an improper degree of correlation and by an improper treatment of the exchange

Additional details

Publishing Information

Journal Title
Physical Review. A
Journal Volume
46
Journal Issue
1
Journal Page Range
p. 186-193.
ISSN
1050-2947
CODEN
PLRAAN

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
24021098
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ELECTRON CORRELATION; ELECTRON-MOLECULE COLLISIONS; NITROGEN; POTENTIALS; RESONANCE; SCATTERING; WAVE FUNCTIONS
Descriptors DEC
COLLISIONS; CORRELATIONS; ELECTRON COLLISIONS; ELEMENTS; FUNCTIONS; MOLECULE COLLISIONS; NONMETALS