Published April 9, 1980
| Version v1
Journal article
EPR detection of (CF3)3CI-. A test case regarding the stability of RX- radical anions
Creators
Description
The presence of the radical anion (CF3)3Cl- was detected by the ESR analysis of a γ-irradiated solution of the compounds at 77 K in a 2-methyltetrahydrofuran glass. A reaction for its stability with respect to its dissociation modes (R' + X or R- + X') is the extent to which the spin density is shared between the atomic orbitals of the localized three-electron bond with maximum stability attained for homonuclear diatomics such as I- and its congeners. The relative electronegativity is also a factor. 15 references, 1 figure
Additional details
Publishing Information
- Journal Title
- J. Am. Chem. Soc.
- Journal Volume
- 102
- Journal Issue
- 8
- Series
- J. Am. Chem. Soc.
- Journal Page Range
- 2860-2861
- ISSN
- 0002-7863
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 13647326
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- ANIONS; CHEMICAL REACTION YIELD; ELECTRON SPIN RESONANCE; ELECTRONEGATIVITY; EXPERIMENTAL DATA; FURANS; LOW TEMPERATURE; ORGANIC CHLORINE COMPOUNDS; ORGANIC FLUORINE COMPOUNDS; ORGANIC IODINE COMPOUNDS; RADICALS; RADIOLYSIS; STABILITY; TEMPERATURE DEPENDENCE
- Descriptors DEC
- CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DATA; DECOMPOSITION; HETEROCYCLIC COMPOUNDS; INFORMATION; IONS; MAGNETIC RESONANCE; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; RADIATION EFFECTS; RESONANCE