Published November 17, 1975 | Version v1
Miscellaneous Metadata-only

Kinetic investigation of the isotope exchange on bis(salicyl aldiminato) copper(II) complexes with copper 64

Creators

Description

The kinetics of the central atom exchange between bis(N-R, 3-x3, 5-x5 salicyl aldiminato)copper(II) complexes and Cu64 labelled CuAc2 x Py in chloroform were investigated. The exchange rate was traced in dependence of the concentration of the reaction partner and of the temperature. It is assumed that the reaction leads to a dimeric product. (HPH)

Availability note (English)

Available from the library of the TH Darmstadt.

Abstract (German)

Es wurde die Kinetik des Zentralatomaustausches zwischen Bis(N-R, 3-x3, 5-x5 salicylaldiminato)Kupfer(II)-Komplexen und 64Cu markiertem CuAc2 x Py in Chloroform untersucht. Die Austauschgeschwindigkeit wurde in Abhaengigkeit von der Konzentration der Reaktionspartner und von der Temperatur verfolgt. Es wird angenommen, dass die Reaktion zu einem dimeren Produkt fuehrt. (HPH)

Additional details

Additional titles

Original title (German)
Kinetische Untersuchung des Isotopenaustausches an Bis(salicylaldiminato)kupfer(II)-Komplexen mit Kupfer-64

Publishing Information

Imprint Pagination
275 p.

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
8312257
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Thesis, Non-conventional Literature
Descriptors DEI
AMINES; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; CHLOROFORM; COPPER COMPLEXES; COPPER 64; ISOTOPIC EXCHANGE; LABELLED COMPOUNDS; ORGANIC COMPOUNDS; TRACER TECHNIQUES
Descriptors DEC
BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; BETA-PLUS DECAY RADIOISOTOPES; COMPLEXES; COPPER ISOTOPES; ELECTRON CAPTURE RADIOISOTOPES; HOURS LIVING RADIOISOTOPES; INTERMEDIATE MASS NUCLEI; ISOTOPE APPLICATIONS; ISOTOPES; KINETICS; NUCLEI; ODD-ODD NUCLEI; ORGANIC CHLORINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RADIOACTIVE MATERIALS; RADIOISOTOPES; REACTION KINETICS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
133 refs.; with figs. and tabs.