Published March 15, 1986
| Version v1
Journal article
Structure of bis(cyclo-triphosphate) of nickel(II) and of tetrasodium hexahydrate
Creators
- 1. Faculte des Sciences et Techniques, Monastir (Tunisia). Dept. de Chimie
Description
Na4Ni(P3O9)2.6H2O, Msub(r)=732.6, triclinic, Panti 1, a=9.186 (2), b=8.020 (2), c=6.838 (1) A, α=89.17 (1), β=102.89 (1), γ=98.03 (1)0, V=486.2 A3, Z=1, Dsub(m)=2.438 (5), Dsub(x)=2.441 Mg m-3, lambda(MoKα)=0.7107 A, μ=1.649 mm-1, F(000)=366, T=293 K, final R=0.036 for 1783 independent reflexions. The nickel atom is octahedrally surrounded by six water molecules. The P3O93- ring anions are linked by a three-dimensional network of sodium polyhedra. Edge-sharing NaO6 sodium polyhedra link so as to form linear chains running parallel to the a+c direction. Sodium polyhedra are connected to nickel octahedra [Ni(H2O)6]2+ via O(W1) water molecules. (orig.)
Additional details
Additional titles
- Original title (French)
- Structure du bis(cyclo-triphosphate) de nickel(II) et de tetrasodium hexahydrate
Publishing Information
- Journal Title
- Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
- Journal Volume
- 42
- Journal Issue
- 3
- Series
- Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
- Journal Page Range
- 268-270
- ISSN
- 0108-2701
- CODEN
- ACSCE
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 17052801
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BOND ANGLE; CRYSTAL STRUCTURE; EXPERIMENTAL DATA; HYDRATES; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MEDIUM TEMPERATURE; NICKEL PHOSPHATES; SODIUM PHOSPHATES; TRICLINIC LATTICES; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; DATA; DIFFRACTION; DISTANCE; INFORMATION; NICKEL COMPOUNDS; NUMERICAL DATA; OXYGEN COMPOUNDS; PHOSPHATES; PHOSPHORUS COMPOUNDS; SCATTERING; SODIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS