Published February 2015 | Version v1
Journal article Metadata-only

Synthesis of new structurally related cyanamide compounds LiM(CN2)2 where M is Al3+, In3+ or Yb3+

Creators

  • 1. Abteilung für Festkörperchemie und Theoretische Anorganische Chemie, Institut für Anorganische Chemie, Auf der Morgenstelle 18, Universität Tübingen, 72076 Tübingen (Germany)
  • 2. Fachhochschule Münster, Labor für Angewandte Materialwissenschaft, Stegerwaldstrasse 39, D-48565 Steinfurt (Germany)

Description

Highlights: • New cyanamide compounds LiM(CN2)2 where M is Al3+, In3+ or Yb3+. • New luminescent material LiIn(CN2)2:Tb3+. • Reduction in efficiency of luminescence with temperature increase. - Abstract: New ternary cyanamide compounds isostructural to LiY(CN2)2 were obtained by solid state metathesis reaction. The crystal structure of LiAl(CN2)2 was determined by single crystal X-ray diffraction, the structures of LiIn(CN2)2 and LiYb(CN2)2 were solved from X-ray powder diffraction data. Photoluminescence properties of Tb3+-doped LiIn(CN2)2 are reported too

Availability note (English)

Available from http://dx.doi.org/10.1016/j.materresbull.2014.10.073

Additional details

Identifiers

DOI
10.1016/j.materresbull.2014.10.073;
PII
S0025-5408(14)00679-5;

Publishing Information

Journal Title
Materials Research Bulletin
Journal Volume
62
Journal Page Range
p. 37-41
ISSN
0025-5408
CODEN
MRBUAC

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
46126696
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ALUMINIUM IONS; CARBON NITRIDES; CRYSTAL STRUCTURE; CYANIDES; DOPED MATERIALS; INDIUM IONS; LITHIUM COMPOUNDS; MONOCRYSTALS; PHOTOLUMINESCENCE; REDUCTION; SOLIDS; SYNTHESIS; TEMPERATURE DEPENDENCE; TERBIUM IONS; X-RAY DIFFRACTION; YTTERBIUM IONS
Descriptors DEC
ALKALI METAL COMPOUNDS; CARBON COMPOUNDS; CHARGED PARTICLES; CHEMICAL REACTIONS; COHERENT SCATTERING; CRYSTALS; DIFFRACTION; EMISSION; IONS; LUMINESCENCE; MATERIALS; NITRIDES; NITROGEN COMPOUNDS; PHOTON EMISSION; PNICTIDES; SCATTERING

Optional Information

Copyright
Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.