Published September 10, 1979
| Version v1
Journal article
Resonant multiphoton dissociation and mechanism of excitation for ethyl chloride
Creators
- 1. Department of Chemistry, University of California, and Materials and Molecular Research Division of the Lawrence Berkeley Laboratory, Berkeley, California 94720
Description
Multiphoton dissociation of ethyl chloride was studied using a tunable 3.3-μm laser to excite CH stretches. Resonances in multiphoton dissociation yields match the position and shape of peaks in the fundamental, as narrow as 0.4 cm-1, and first-and second-overtone absorption spectra. Transitions through the discrete levels occur at or near resonance. Anharmonicity is compensated by the presence of five CH stretch modes
Additional details
Publishing Information
- Journal Title
- Phys. Rev. Lett.
- Journal Volume
- 43
- Journal Issue
- 11
- Series
- Phys. Rev. Lett.
- Journal Page Range
- 761-764
- ISSN
- 0031-9007
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 11511650
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; DISSOCIATION; EXCITATION; GAS CHROMATOGRAPHY; LASER RADIATION; LOW PRESSURE; MOLECULES; NEODYMIUM LASERS; ORGANIC CHLORINE COMPOUNDS; PHOTOLYSIS; PHOTON COLLISIONS; PHOTONS; PULSES; RESONANCE
- Descriptors DEC
- AMPLIFIERS; CHEMICAL REACTIONS; CHROMATOGRAPHY; COLLISIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; ELEMENTARY PARTICLES; ENERGY-LEVEL TRANSITIONS; LASERS; MASSLESS PARTICLES; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RADIATIONS; SEPARATION PROCESSES; SOLID STATE LASERS; SPECTRA