Published October 1993
| Version v1
Journal article
Adiabatic states of two-atomic molecules in the strong spin-orbital interaction
Description
The paper deals with the states of two-atom molecule in case of Gundu C-type bond. Hamiltonian and adiabatic wave functions are obtained, symmetry properties are analyzed. It is shown that spin-orbital interaction is not small in case of basic singlet terms of a number of molecules whose nuclei charges exceed 10. Selection rules are established for nonadiabatic and radiation transitions between adiabatic and nonadiabatic relativistic states. 9 refs., 3 figs
Additional details
Additional titles
- Original title (Russian)
- Адиабатические состояния двухатомных молекул в условиях сильного спин-орбитального взаимодействия
Publishing Information
- Journal Title
- Optika i Spektroskopiya
- Journal Volume
- 75
- Journal Issue
- 4
- Journal Page Range
- p. 717-729.
- ISSN
- 0030-4034
- CODEN
- OPSPAM
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 25046169
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ABSORPTION; ADIABATIC APPROXIMATION; COUPLING CONSTANTS; ELECTRONS; ENERGY-LEVEL TRANSITIONS; HAMILTONIANS; L-S COUPLING; MOLECULES; RELATIVISTIC RANGE; ROTATIONAL STATES; SELECTION RULES; SPIN; VIBRATIONAL STATES
- Descriptors DEC
- ANGULAR MOMENTUM; COUPLING; ELEMENTARY PARTICLES; ENERGY LEVELS; ENERGY RANGE; EXCITED STATES; FERMIONS; INTERMEDIATE COUPLING; LEPTONS; MATHEMATICAL OPERATORS; PARTICLE PROPERTIES; QUANTUM OPERATORS; SORPTION