Published May 1985 | Version v1
Journal article

Determination of the enthalpy of formation of ions UOF5 and UO2F3 by the method of ionic-molecular equilibrium

  • 1. Institute of High Temperatures, Academy of Sciences of the USSR

Description

Knudsen's effusion method is used in combination with mass-spectrographic recording of ions effusing from a cell in a vapor over uranyl fluoride to record ions UOF5- and UO2F3- and to study ionic molecular equilibrium with the participation of these ions. Their enthalpies of formation are obtained: ΔH0 /sub f/ 0(UOF5-) '' -2530 + or 40 kJ. mole-1, ΔH0 /sub f/ 0(UO2F3-) = -2090 + or - 40 kJ. mole-1

Additional details

Publishing Information

Journal Title
High Temp. (Engl. Transl.)
Journal Volume
22
Journal Issue
6
Series
High Temp. (Engl. Transl.).
Journal Page Range
857-861
ISSN
0018-151X
CODEN
HITEA

Optional Information

Notes
Translated from Teplofizika Vysokikh Temperatur, Vol. 22, No. 6, pp. 1120-1124, November-December, 1984.. Cover-to-cover translation of Teplofizika Vysokikh Temperatur (USSR).