A white light phosphor suitable for near ultraviolet excitation

Luminescent properties of Eu2+-doped phosphors with nominal composition of 2SrO.MgO.xSiO2 (0.8≤x≤1.2) are studied. The emission spectra consist of a blue band (460 nm) and a yellow band (550 nm), the relative intensities of which change with the SiO2 composition x. It is found that a combination of the blue and yellow bands can generate white light at x around 1 under near- ultraviolet excitation. X-ray diffraction patterns of the phosphors demonstrate both Sr3MgSi2O8 and Sr2SiO4 phases, in which Eu2+ contributes to the blue and yellow emissions, respectively. The relative intensity variation of the two bands is attributed to the relative proportion of the two phases dependent on SiO2 composition. A white light emitting diode fabricated using a GaN chip (λem=400 nm) and this phosphor is obtained, exhibiting color coordinates of x=0.33, y=0.34, color rendering index of 85 and luminous efficiency of 6 lm/W