Phase diagram analysis of (U,Pu)O2-x sub-system

The high plutonium, hypo-stoichiometric fuel exists as two phase system at low temperatures. The partial phase diagram of (U,Pu)O2-x with two coexisting cubic phases was extensively investigated in this work using theoretical models. The critical temperature of the miscibility gap varies with Pu/M and O/M of the system. Based on the similar miscibility gap behaviour observed in PuO2-x system and the experimental data available on the phase boundaries of (U,Pu)O2-x for various Pu/M, some semi-empirical relationships and solution models were developed. With the help of these relationships, ternary isothermal sections of the miscibility gap, O/M at different temperatures and the critical temperature of the miscibility gap of (U,Pu)2-x for different Pu/M values were calculated. These calculated values were compared with the available literature data