Published March 2000
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Inclusion polymerization of vinyl chloride monomer in deoxycholic acid host via γ-ray irradiation
- 1. The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok (Thailand)
- 2. Department of Macromolecular Science, Case Western Reserve University, Cleveland, OH (United States)
Description
Inclusion polymerization of vinyl chloride monomer (VCM) was studied in the system of 3α, 12α -dihydroxy-5β-cholan-24-oic acid (deoxycholic acid, DCA). DCA-VCM inclusion compound system was originally prepared by guest intercalation technique in DCA guest free crystal. The inclusion polymerization of DCA-VCM by γ-irradiation at total dose 2 Mrad, gives a syndiotactic rich polyvinyl chloride (PVC) as can be confirmed by FT-IR and FT-NMR. (author)
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Additional details
Publishing Information
- Imprint Title
- Proceedings of the Takasaki workshop on bilateral cooperations. Radiation Processing of natural polymers
- Imprint Pagination
- 184 p.
- Journal Page Range
- p. 160-173
- Report number
- JAERI-Conf--2000-003
Conference
- Title
- Takasaki workshop on bilateral cooperations. Radiation processing of natural polymers
- Dates
- 1-2 Nov 1999
- Place
- Takasaki, Gunma (Japan)
INIS
- Country of Publication
- Japan
- Country of Input or Organization
- Japan
- INIS RN
- 32004919
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- CHOLIC ACID; FOURIER TRANSFORM SPECTROMETERS; GAMMA RADIATION; INCLUSIONS; INFRARED SPECTRA; IRRADIATION; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; PVC; RADIATION DOSES; RADIATION EFFECTS; STEREOCHEMISTRY; VINYL CHLORIDE; VINYL MONOMERS
- Descriptors DEC
- BILE ACIDS; CARBOXYLIC ACIDS; CHEMICAL REACTIONS; CHLORINATED ALIPHATIC HYDROCARBONS; DOSES; ELECTROMAGNETIC RADIATION; HALOGENATED ALIPHATIC HYDROCARBONS; HYDROXY COMPOUNDS; IONIZING RADIATIONS; MAGNETIC RESONANCE; MEASURING INSTRUMENTS; MONOMERS; ORGANIC ACIDS; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC POLYMERS; POLYMERS; POLYVINYLS; RADIATIONS; RESONANCE; SPECTRA; SPECTROMETERS; STEROIDS; STEROLS
Optional Information
- Notes
- 5 refs., 13 figs., 1 tab.