Surface-enhanced Raman scattering of dipolar molecules by the graphene Fermi surface modulation with different dipole moments

Graphical abstract: The Raman spectrum of chromophore/graphene hybrids with different dipole molecules has been investigated. It is shown that the graphene-enhanced Raman scattering (GERS) can be significantly changed by the dipole moment values. By the analysis of the Raman signals of graphene as well as the interfacial energy level match, a strong correlation between the GERS and graphene Fermi surface is revealed. - Highlights: • Raman spectrums of chromophore/graphene hybrids with different dipole moments by changing the terminal groups are studied. • The surface-enhanced Raman scattering shows significant positive correlation with the dipole moment. • Dipole moment of chromophoreis found crucialin the interfacialenergy level matching by regulating graphene Fermi level. - Abstract: We report the modulation of Raman scattering spectrum of chromophore/graphene hybrids by tunning the molecular polarization with different terminal groups (methyl, methoxy, nitrile, and two nitros). Based on the density functional theory, the specific dipole moment values of the chromophore molecules are calculated. An obvious surface-enhanced Raman scattering (SERS) was observed and the scattering intensity of molecule increases with enlarged dipole moment. According to the analysis of G band Raman shifts of graphene, the enhancement of the Raman signal can be attributed to strong electronic coupling between graphene and chromophore, which is closely related with the modulation of graphene Fermi surface by changing the dipole moment of the molecule. Besides, the optimization of the ground state geometry and the binding energy of the hybrids were also calculated with the Density Functional Based Tight Bonding (DFTB) method, which confirms that the enhanced Raman scattering of molecules on graphene arises from the improved energy level matching between graphene Fermi surface and molecular band, further providing a new way to design novel SERS devices.