Published November 1996 | Version v1
Journal article

Crystal and molecular structure of a complex between 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane and 2,4-dinitro-2,4-diazapentane

  • 1. Russian State Scientific Center 'Karpov Research Institute of Physical Chemistry', ul. Vorontsovo Pole 10, Moscow, 103064 (Russian Federation)

Description

A molecular complex between 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (I) and 2,4-dinitro-2,4-diazapentane (II) was obtained, and its x-ray crystal structure was determined. Crystals of the complex are monoclinic. The unit-cell parameters are: a=10.720(3), b=11.683(3), and c=11.098(3) A; γ=114.55(2) deg.; V=1264.3(5) A 3; sp. gr. P21/n; and Z=4. The composition of the complex is I:II=1:2. The molecular conformation of I in the complex is close to that observed in the β-form of I. Intermolecular contacts of I and II in the complex correspond to normal van der Waals interactions

Additional details

Publishing Information

Journal Title
Crystallography Reports
Journal Volume
41
Journal Issue
6
Journal Page Range
p. 963-965
ISSN
1063-7745
CODEN
CYSTE3

Optional Information

Notes
Translated from Kristallografiya, ISSN 0023-4761, 41, 1015-1017 (November-December 1996); (c) 1996 MAIK/Interperiodika