Characterization of a nylon 6/poly(methyl acrylate): copolymer produced by radiation grafting

Acrylic acid has been grafted onto nylon 6 by the mutual γ-irradiation technique. Methods are described for removing poly(acrylic acid) homopolymer and ungrafted nylon, the latter involving intermediate conversion to the calcium ionomer. The pure graft copolymer in its methylated form, viz., nylon 6/poly(methyl acrylate), NY/PMA, was characterized by light scattering in mixed solvents to yield the true molecular weight (3.2 x 106) as well as the molecular weights M/sub PMA/ (domain) and M/sub NY/ (domain) of the PMA and NY portions, respectively. The molecular weight M/sub PMA/ of the grafts was measured after hydrolysis of the backbone, and the molecular weight M/sub NY/ of the backbone was determined via a previously devised indirect procedure. Comparisons of M/sub PMA/ (domain) with M/sub PMA/ and of M/sub NY/ (domain) with M/sub NY/ gave approx. 7 nylon chains and approx. 17 poly(methyl acrylate) chains per copolymer molecule. Chain transfer and bimolecular termination during grafting are proposed as probable contributory factors to the branched structure of the copolymer