Published July 2013 | Version v1
Journal article

Pressure dependence on the viscosities of 1-butyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide and two tris(pentafluoroethyl)trifluorophosphate based ionic liquids: New measurements and modelling

  • 1. Laboratorio de Propiedades Termofísicas, Departamento de Física Aplicada, Campus Vida, Universidad de Santiago de Compostela, E-15782 Santiago de Compostela (Spain)

Description

Highlights: ► Viscosities of 3 ILs from 313.15 to 363.15 K at pressures up to 150 MPa are reported. ► Temperature and pressure correlations with modified VFT and Litovitz equations are provided. ► Local pressure–viscosity coefficient is studied for 9 ILs and other liquids. ► Density scaling concept is applied to the reduced and non-reduced viscosity for 6 ILs. -- Abstract: New experimental viscosity values for three ionic liquids, 1-butyl-2,3-dimethylimidazolium tris(pentafluoroethyl)trifluorophosphate, 1-(2-methoxyethyl)-1-methyl-pyrrolidinium tris(pentafluoroethyl)trifluorophosphate and 1-butyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide, are reported in this work. The measurements were carried out using a falling-body viscometer within the temperature range from (313.15 to 363.15) K at pressures up to 150 MPa. These values were correlated as a function of temperature and pressure with four different equations. Moreover, we perform an analysis of the dependency of viscosity on pressure and temperature based on the density scaling concept for these fluids and other three ionic liquids recently studied with the same device

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2013.02.014

Additional details

Identifiers

DOI
10.1016/j.jct.2013.02.014;
PII
S0021-9614(13)00084-0;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
62
Journal Page Range
p. 162-169
ISSN
0021-9614
CODEN
JCTDAF

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
45053465
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
LIQUIDS; MOLTEN SALTS; PRESSURE DEPENDENCE; PRESSURE RANGE MEGA PA 10-100; SIMULATION; TEMPERATURE DEPENDENCE; VISCOSITY
Descriptors DEC
FLUIDS; PRESSURE RANGE; PRESSURE RANGE MEGA PA; SALTS

Optional Information

Copyright
Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.