Pressure dependence on the viscosities of 1-butyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide and two tris(pentafluoroethyl)trifluorophosphate based ionic liquids: New measurements and modelling
- 1. Laboratorio de Propiedades Termofísicas, Departamento de Física Aplicada, Campus Vida, Universidad de Santiago de Compostela, E-15782 Santiago de Compostela (Spain)
Description
Highlights: ► Viscosities of 3 ILs from 313.15 to 363.15 K at pressures up to 150 MPa are reported. ► Temperature and pressure correlations with modified VFT and Litovitz equations are provided. ► Local pressure–viscosity coefficient is studied for 9 ILs and other liquids. ► Density scaling concept is applied to the reduced and non-reduced viscosity for 6 ILs. -- Abstract: New experimental viscosity values for three ionic liquids, 1-butyl-2,3-dimethylimidazolium tris(pentafluoroethyl)trifluorophosphate, 1-(2-methoxyethyl)-1-methyl-pyrrolidinium tris(pentafluoroethyl)trifluorophosphate and 1-butyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide, are reported in this work. The measurements were carried out using a falling-body viscometer within the temperature range from (313.15 to 363.15) K at pressures up to 150 MPa. These values were correlated as a function of temperature and pressure with four different equations. Moreover, we perform an analysis of the dependency of viscosity on pressure and temperature based on the density scaling concept for these fluids and other three ionic liquids recently studied with the same device
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2013.02.014Additional details
Identifiers
- DOI
- 10.1016/j.jct.2013.02.014;
- PII
- S0021-9614(13)00084-0;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 62
- Journal Page Range
- p. 162-169
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 45053465
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- LIQUIDS; MOLTEN SALTS; PRESSURE DEPENDENCE; PRESSURE RANGE MEGA PA 10-100; SIMULATION; TEMPERATURE DEPENDENCE; VISCOSITY
- Descriptors DEC
- FLUIDS; PRESSURE RANGE; PRESSURE RANGE MEGA PA; SALTS
Optional Information
- Copyright
- Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.